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宋體;">在線(xiàn)氯離子分析儀用于鍋爐給水，節熱器，冷凝器等高純度水質(zhì)中氯離子值的連續監測。也可以用于要求較高的自來(lái)水氯離子的連續測量。<br /><span style="font-family: 宋體;">儀器工作原理：</span></span></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">固態(tài)電極膜內使用的是相對不可溶的無(wú)機鹽。固態(tài)電極以同類(lèi)和異類(lèi)方式存在。這兩種類(lèi)型都由于離子交換過(guò)程而在膜上形成電勢。此類(lèi)電極包括銀/硫離子、鉛離子、銅離子、氯化物、硫氯酸根、氯離子和氯離子選擇性電極。</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">電極的準確性和穩定性怎樣，是決定離子計好壞的關(guān)鍵因素之一。特別是低電導率水質(zhì)，對電極的要求更高。若用普通的電極來(lái)測量，穩定性很差，而且使用壽命又短，滿(mǎn)足不了要求。</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">離子選擇性電極（ISEs）是以敏感膜為基礎的電化學(xué)傳感器，這層膜是使電極對特定離子有選擇性響應的元件。</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">根據膜的材料不同可將離子選擇性電極分為4種：</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">•</span></span> <span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">玻璃膜（如Na</span></span><sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">+</span></span></sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">） •</span></span> <span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">固態(tài)膜（如Pb</span></span><sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">2+</span></span></sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">）</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">•</span></span> <span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">聚合體膜（如K</span></span><sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">+</span></span></sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">） •</span></span> <span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">氣體滲透膜（如CO</span></span><sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">2</span></span></sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">）</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">電極置于溶液內時(shí)膜上會(huì )形成一電勢差。當樣品內待測離子的濃度變化時(shí)，用離子選擇性電極和一內置或外置參比電極一起使用能測出此電勢差的變化。從原理上說(shuō)，整個(gè)的設置可以作如下描述：</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">該測得的電勢E和樣品內的離子活躍度ai之間的關(guān)系用Nernst數學(xué)方式可表述如下：</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">E=E</span></span><sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">0 </span></span></sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">+ 斜率·loga</span></span><sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">i</span></span></sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;"> （斜率等于2.3 RT/ZiF）</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">其中：R為氣體常量，8.314JK-1mol-1</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">T為溫度K</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">F是法拉第等值，9.6487×104 Cmol-1</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">Zi是所測離子的電荷</span></span></p></span><p><span style="font-size: 14px;"><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">該斜率在25℃下為59.16mV/Zi。如所測離子是像鉀離子那樣的單價(jià)離子（Zi＝＋1），在濃度發(fā)生十進(jìn)制變化時(shí)，25℃時(shí)可以觀(guān)察到59.16mV的電勢變化。類(lèi)似的，像鈣離子那樣的二價(jià)離子（Zi＝＋2）在25℃下可觀(guān)察到59.16mV/2＝29.58mV的電勢變化。</span></span> </span></p><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">E</span></span><sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">0</span></span></sub><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">是每一支離子選擇性電極與特定參比結合時(shí)的恒定的電勢差。ai是離子活度，但只在較稀釋的溶液內和離子濃度相等。離子的活度取決于由離子內容決定的樣品溶液中的離子強度。</span></span></p></span><p> </p><span style="font-size: 14px;"><p><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">所測離子的濃度在其高低端都會(huì )發(fā)生線(xiàn)性偏移，該偏移決定了測量的高低端的限度。離子電極可以精確測量到濃度為10</span></span><sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">-6</span></span></sup><span style="color: rgb(0, 0, 0);"><span style="font-family: 宋體;">M的樣品溶液。高濃度情況下（通常高于0.1M）線(xiàn)性偏移是由于帶相反電荷的離子的作用引起的。</span></span></p></span><p><span style="font-size: 14px;"><span style="font-family: 宋體;">儀表特點(diǎn)：</span></span></p><table style="border-collapse:collapse; margin-left:6.7500pt; margin-right:6.7500pt; width:660px"> <tbody> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">顯示</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">192X64 點(diǎn)陣液晶</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">測量范圍</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">(0~</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">9)PF -------0~3550mg/L</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">顯示精度</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">1ug/L或者 0.01mg/L或者0.01g/L</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">電氣精度</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">±3%F.S</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">溫度補償范圍</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">( 0~</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">6</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">0) ºC</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">水樣流速</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">(50~300)mL/</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">分鐘</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">反應時(shí)間</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">《60S（</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">25ºC</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">）</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">電源</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">交流90~265v 直流 12-30V</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">防護等級</span></span></span></strong> </p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">IP66</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">外形尺寸</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">144</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">(L) × </span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">144</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">(W) × </span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">105</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:arial">(H)</span></span></span></strong><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">毫米</span></span></span></strong></p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">重量</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">1公斤</span></span></span></strong> </p> </td> </tr> <tr> <td style="vertical-align:center; width:177px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">質(zhì)保期</span></span></span></strong></p> </td> <td style="vertical-align:center; width:483px"> <p><strong><span style="font-size:9pt"><span style="color:#000000"><span style="font-family:宋體">非損耗品12個(gè)月</span></span></span></strong></p> </td> </tr> </tbody></table><p> </p><p> </p> </div> <div id="47vml93" class="lyNyProDetail_ConTit" id="cpzx"><p>產(chǎn)品咨詢(xún)</p></div> <div id="bczglx4" class="ly_msg"> <link rel="stylesheet" type="text/css" href="/css/MessageBoard_style.css"> <script language="javascript" src="/skins/Scripts/order.js?v=20210318" 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value="26">天津</option> <option value="27">新疆</option> <option value="28">西藏</option> <option value="29">云南</option> <option value="30">浙江</option> <option value="31">重慶</option> <option value="32">香港</option> <option value="33">澳門(mén)</option> <option value="34">中國臺灣</option> <option value="35">國外</option> </select></div> </li> <li> <h4>詳細地址：</h4> <div id="dvbcj43" class="msg_ipt12"><input class="textborder" size="50" name="addr" id="addr" placeholder="請輸入您的詳細地址"/></div> </li> <li> <h4>補充說(shuō)明：</h4> <div id="nqnzbik" class="msg_ipt12 msg_ipt0"><textarea class="areatext" style="width:100%;" name="message" rows="8" cols="65" id="message" placeholder="請輸入您的任何要求、意見(jiàn)或建議"></textarea></div> </li> <li> <h4 class="xh">驗證碼：</h4> <div id="3tp3pbi" class="msg_ipt2"> <div id="wfhmozv" class="c_yzm"> <input class="textborder" size="4" name="Vnum" id="Vnum"/> <a href="javascript:void(0);" class="yzm_img"><img src="/Image.aspx" title="點(diǎn)擊刷新驗證碼" onclick="this.src='/image.aspx?'+ 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